Joseph W. Lyding – Lyding Group

(217) 333-8370
lyding@illinois.edu
3114 Micro & Nanotechnology Lab

Biography

After being recruited to Illinois in 1984 by John Bardeen to work on the 1D charge density wave problem, Professor Joe Lyding constructed the first atomic-resolution scanning tunneling microscope (STM) in the Midwestern United States and one of the earliest STMs in the US. He followed this by inventing an ultra-stable STM in 1987 that was patented (US Patent 4,841,148) and licensed by the University of Illinois to RHK and McAllister Technical Services. Lyding’s design has been copied worldwide and has also been included in major textbooks on surface science.

In 1994 Lyding developed a novel new STM-based nanofabrication scheme and achieved atomic resolution patterning of silicon surfaces through the selective desorption of hydrogen atoms. This method was immediately recognized and copied worldwide with Lyding giving scores of invited and several plenary talks. His initial paper on the subject [Appl. Phys. Lett. 64, 2010 (1994)] has been cited 518 times. Lyding’s initial work uncovered the fact that there were two distinct physical phenomena associated with the hydrogen desorption process. This led to collaboration with Dr. Phaedon Avouris at IBM who modeled these processes. Lyding was recognized with an IBM Partnership Award in 1996, which led to a further study of the desorption process with a cryogenic ultrahigh vacuum (UHV) STM constructed in Lyding’s lab. [Physical Review Letters [80, 1336 (1998), cited 225 times] and the development of feedback-controlled lithography for single-atom precision hydrogen desorption [Nanotechnology 11, 70 (2000), cited 220 times].

In 1995, Lyding discovered a giant isotope effect when hydrogen was replaced by deuterium on silicon surfaces, in an experiment suggested by Avouris. STM desorption studies showed that deuterium was two orders of magnitude more difficult to desorb than hydrogen. This was published in Chemical Physical Letters [257, 148 (1996)] and Surface Science [363, 368 (1996)] with 163 and 172 citations respectively. In a meeting with Professor Karl Hess, Lyding made the connection between the isotope effect he had observed in the STM experiments and the hydrogen-related hot-carrier degradation in CMOS transistors. Lyding proposed replacing hydrogen with deuterium in CMOS devices to see if the same isotope effect could reduce the degradation. Lyding and Hess worked with Dr. Isik Kizilyalli of Lucent to treat commercial CMOS chips in deuterium and their initial results showed a dramatic 50x reduction in hot-carrier degradation. Their first paper [Lyding, Hess and Kizilyalli, Appl. Phys. Lett. 68, 2526 (1996)] has been cited 372 times. This result was met with major publicity and was rapidly confirmed by industrial laboratories worldwide. Deuterium has been used in commercial production by several major chip manufacturers, most recently by Samsung, under license from the University of Illinois, for the ARM processors used in iPhone and iPad devices. In 1996, Lyding was called to Washington D.C. by Senator Bill Frist to present the deuterium result to a Senate conference forum on science and technology, exploring the unanticipated technology benefits of supporting fundamental research.

In 2001-2002, Lyding began exploring carbon nanotubes on silicon as a potential hybrid approach to using nanotubes. Unfortunately, at that time there was no technique to integrate carbon nanotubes with clean, air-sensitive surfaces. STM studies up until then relied on solution deposition of nanotubes onto inert gold surfaces. To circumvent this problem, Lyding developed a new method that he termed dry contact transfer (DCT) [Appl. Phys. Lett. 83, 5029 (2003), cited 95 times] in which nanotubes could be brought into a UHV environment and then directly stamped onto atomically clean surfaces. Lyding’s group published a number of papers between 2003 and 2007 using DCT to place nanotubes on silicon and III-V compound semiconductor surfaces. In these papers, they noted a strong interaction between nanotube and substrate based on the relative alignment of the nanotube axis and substrate atomic row directions. Strong doping effects and nanotube bandgap changes were also observed, underscoring the detailed complexity of potential technological applications of carbon nanotubes.

In 2007, Lyding extended the DCT method to the study of monolayer graphene on silicon and III-V substrates. His first paper on graphene [Nanotechnology 19, 015704 (2008)] was recognized as one of the most accessed papers in Nanotechnology for 2008. Unlike nanotubes, finite sheets of graphene have edges and it was predicted in 1996 that edges with the so-called zigzag symmetry would exhibit a metallic edge state that should have a pronounced effect on transport through graphene quantum dots or nanoribbons. However, experiments didn’t see this effect leading to postulation in the literature that nonuniformity and edge disorder were obfuscating the observation of edge effects. Through DCT of graphene on silicon, Lyding and graduate student Kyle Ritter demonstrated for the first time the existence of the metallic zigzag edge state. Furthermore, they studied quantum size effects down to 2nm lateral graphene dimensions, an order of magnitude smaller than previous studies. This work was published in Nature Materials [8, 235 (2009), cited 681 times]. Lyding’s most recent work on graphene has demonstrated the admixture of graphene and substrate electron wavefunctions [Nano Lett. 10, 3446 (2010)], silicon-induced metallic states in semiconducting graphene quantum dots [Nano Lett. 11, 2735 (2011)], and that the copper (111) surface is the optimal copper surface for monolayer graphene growth [Nano Lett. 11, 4547 (2011), cited 236 times].

In 2006, Lyding invented a novel process for sharpening conductive probes down to sub-5nm radii. His method, Field-Directed Sputter Sharpening (FDSS), is based on ion sputtering of a biased probe. The probe bias establishes an inhomogeneous electric field at the tip apex that deflects the incoming ions and selectively sharpens the apex, which increases the field strength and enhances the effect. High-performance STM and AFM tips with super hard coatings have now been demonstrated and Lyding is now the Chief Technical Officer of Tiptek, LLC, a new start-up company to commercialize this technology. The US Patent Office has issued FDSS patents (8,070,920 and 8,819,861).

Research Honors

Feynman Prize in Nanotechnology, 2015
AAAS Fellow, 2014
AVS Outstanding Research Award, 2014
NBIC Research Excellence in Nanotechnology Award, 2013
AVS Nanotechnology Recognition Award, 2013
IEEE Pioneer in Nanotechnology Award, 2012
IEEE Fellow, 2011
Poster Award – MRS Meeting, 2006
Best Paper Award – IEEE WMED Workshop, 2005
Best Paper Award – IEEE Workshop on Microelectronics & Electron Devices, 2005
Finalist, Discover Magazine Technical Innovation Award, 2001
Finalist, Feynman Prize in Nanotechnology, 2000
Finalist, Feynman Prize in Nanotechnology, 1999
Fellow, American Vacuum Society, 2000
DARPA Sustained Excellence Award, 1998
Philips Visiting Scholar, Haverford College, 1998
Fellow of APS, 1997
UIUC University Scholar, 1997
Senior Member of IEEE, 1997
IBM Partnership Award, 1996
Associate, Center for Advanced Study, 1996-97
Who’s Who in Science and Engineering
Who’s Who
Arnold O. Beckman Research Award, U Of I, 1989
Beckman Fellow, Center for Advanced Study 1987-88
Arnold O. Beckman Research Award, University of Illinois, 1985
Arnold O. Beckman Research Award, University of Illinois, 1984
Arthur K. Doolittle Award, American Chemical Society, 1983
IBM Postdoctoral Fellow 1983

Public Service Honors

Presented the deuterium processing discovery on behalf of the Science Coalition Senate Republican Conference Issue Forum on Science and Technology, Washington, DC, 25 March 1996.
Presented keynote address at the American Chemical Society High School Teacher’s Night Awards Banquet, Sangamon State University, May 6, 1994, Springfield, IL.